Poonam Negi, Naveen Chandra Joshi, Richa Saxena, Bhupendra Singh Rawat
The incorporation of metal oxide nanoparticles into magnesium oxide (MgO) powder enhances its supercapacitor performance. This study investigates the influence of cooper oxide nanoparticles (CuO-NPs) incorporated into magnesium oxide (MgO) powder on the electrochemical performance of supercapacitors. Magnesium oxide (MgO), Copper Oxide nanoparticles (CuO-NPs), and their composite (MgO/CuO) were synthesized and evaluated under both three- and two-electrode configurations. Structural, morphological, and electrochemical characterizations were performed to assess the effect of CuO addition. X-ray diffraction (XRD) and scanning electron microscopy (SEM) confirmed the successful integration of CuO into the MgO matrix, accompanied by notable changes in crystallinity and particle morphology. Electrochemical performance was evaluated using cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS). The MgO/CuO composite demonstrated a markedly enhanced specific capacitance of 444.4 F/g at 2 A/g in a three-electrode system, significantly higher than individual MgO and CuO. The composite retained 96.8% capacitance after 5000 GCD cycles, showing excellent cyclic stability. EIS results revealed low series resistance, fast ion diffusion, and improved charge-transfer kinetics. The enhanced performance is attributed to the synergistic interaction between MgO and CuO, which improves surface activity, electron transport, and structural stability, thereby establishing MgO/CuO as a promising, cost-effective, and environmentally benign electrode material for next-generation high-performance supercapacitors.