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    Computational prediction of electrical and thermal properties of graphene and BaTiO3 reinforced epoxy nanocomposites

    • Raghvendra Kumar Mishra
    • Saurav Goel
    • Hamed Yazdani Nezhad


    Abstract

    Graphene based materials e.g., graphene oxide (GO), reduced graphene oxide (RGO) and graphene nano platelets (GNP) as well as Barium titanate (BaTiO3) are emerging reinforcing agents which upon mixing with epoxy provides composite materials with superior mechanical, electrical and thermal properties as well as shielding against electromagnetic (EM) radiations. Inclusion of the aforementioned reinforcing agents has shown to improve the performance, however, the extent of improvement has remained uncertain. In this study, a computational modelling approach was adopted using COMSOL Multiphysics software in conjunction with Bayesian statistical analysis to investigate the effects of including various filler materials e.g. GO, RGO, GNP and BaTiO3 in influencing the direct current (DC) conductivity (σ), dielectric constant (ε) and thermal properties on the resulting epoxy polymer matrix composites. The simulation of epoxy composites were performed for different volume percentage of the filler materials by varying the geometry of the filler material. It was observed that the content of GO, RGO, GNPs and the thickness of graphene nanoplatelets can alter the DC conductivity, dielectric constant, and thermal properties of the epoxy matrix. The lower thickness of GNPs was found to offer the larger value of DC conductivity, thermal conductivity and thermal diffusivity than rest of the graphene nanocomposites, while, the RGO showed better dielectric constant value than neat epoxy, and GO, GNP nanocomposites. Similarly, BaTiO3 nanoparticles content and diameter were observed to alter the dielectric constant, DC conductivity and thermal properties of modified epoxy in several order magnitude than neat epoxy. In this way, the higher diameter particles of BaTiO3 showed better DC conductivity properties, dielectric constant value, thermal conductivity and thermal diffusivity. Moreover, this research provides guidance for further computational examination on the selection of GNP and BaTiO3 materials for the enhancement of the electrical and thermal properties of the epoxy matrix.

    Keywords: Epoxy Barium titanate Graphene nanoplatelets Dielectric properties Thermal properties
    Section

    References

    1. Atif, R., Shyha, I., & Inam, F. (2016). Mechanical, thermal, and electrical properties of graphene-epoxy nanocomposites-A review. In Polymers. https://doi.org/10.3390/polym8080281
    2. Barber, P., Balasubramanian, S., Anguchamy, Y., Gong, S., Wibowo, A., Gao, H., Ploehn, H. J., & Loye, H. C. Zur. (2009). Polymer composite and nanocomposite dielectric materials for pulse power energy storage. Materials. https://doi.org/10.3390/ma2041697
    3. Bauhofer, W., & Kovacs, J. Z. (2009). A review and analysis of electrical percolation in carbon nanotube polymer composites. Composites Science and Technology, 69(10), 1486–1498. https://doi.org/10.1016/j.compscitech.2008.06.018
    4. Bikky, R., Badi, N., & Bensaoula, A. (2010). Effective Medium Theory of Nanodielectrics for Embedded Energy Storage Capacitors. Comsol.De.
    5. Caradonna, A., Badini, C., Padovano, E., & Pietroluongo, M. (2019). Electrical and thermal conductivity of epoxy-carbon filler composites processed by calendaring. Materials. https://doi.org/10.3390/ma12091522
    6. Carotenuto, G., Romeo, V., Cannavaro, I., Roncato, D., Martorana, B., & Gosso, M. (2012). Graphene-polymer composites. IOP Conference Series: Materials Science and Engineering. https://doi.org/10.1088/1757-899X/40/1/012018
    7. Chikhi, M., Agoudjil, B., Haddadi, M., & Boudenne, A. (2013). Numerical modelling of the effective thermal conductivity of heterogeneous materials. Journal of Thermoplastic Composite Materials. https://doi.org/10.1177/0892705711424921
    8. Cho, K. S. (2016). Polymer physics. In Springer Series in Materials Science. https://doi.org/10.1007/978-94-017-7564-9_4
    9. Cho, S. D., Lee, S. Y., Hyun, J. G., & Paik, K. W. (2005). Comparison of theoretical predictions and experimental values of the dielectric constant of epoxy/BaTiO3 composite embedded capacitor films. Journal of Materials Science: Materials in Electronics. https://doi.org/10.1007/s10854-005-6454-3
    10. Ekanath, D. M., Badi, N., & Bensaoula, A. (2011). Modeling and Simulation of Artificial Core-Shell Based Nanodielectrics for Electrostatic Capacitors Applications. Comsol Conference.
    11. Friedrich, K., & Almajid, A. A. (2013). Manufacturing Aspects of Advanced Polymer Composites for Automotive Applications. Applied Composite Materials, 20(2), 107–128. https://doi.org/10.1007/s10443-012-9258-7
    12. Galpaya, D., Wang, M., Liu, M., Motta, N., Waclawik, E., & Yan, C. (2012). Recent Advances in Fabrication and Characterization of Graphene-Polymer Nanocomposites. Graphene, 01(02), 30–49. https://doi.org/10.4236/graphene.2012.12005
    13. Gresil, M., Wang, Z., Poutrel, Q. A., & Soutis, C. (2017). Thermal Diffusivity Mapping of Graphene Based Polymer Nanocomposites. Scientific Reports. https://doi.org/10.1038/s41598-017-05866-0
    14. Hass, J., De Heer, W. A., & Conrad, E. H. (2008). The growth and morphology of epitaxial multilayer graphene. In Journal of Physics Condensed Matter. https://doi.org/10.1088/0953-8984/20/32/323202
    15. Hou, H., Dai, W., Yan, Q., Lv, L., Alam, F. E., Yang, M., Yao, Y., Zeng, X., Xu, J. Bin, Yu, J., Jiang, N., & Lin, C. Te. (2018). Graphene size-dependent modulation of graphene frameworks contributing to the superior thermal conductivity of epoxy composites. Journal of Materials Chemistry A. https://doi.org/10.1039/c8ta03937b
    16. Jarosinski, L., Rybak, A., Gaska, K., Kmita, G., Porebska, R., & Kapusta, C. (2017). Enhanced thermal conductivity of graphene nanoplatelets epoxy composites. Materials Science- Poland. https://doi.org/10.1515/msp-2017-0028
    17. Kargar, F., Barani, Z., Salgado, R., Debnath, B., Lewis, J. S., Aytan, E., Lake, R. K., & Balandin, A. A. (2018). Thermal Percolation Threshold and Thermal Properties of Composites with High Loading of Graphene and Boron Nitride Fillers. ACS Applied Materials and Interfaces. https://doi.org/10.1021/acsami.8b16616
    18. Kim, D. S., Baek, C., Ma, H. J., & Kim, D. K. (2016). Enhanced dielectric permittivity of BaTiO3/epoxy resin composites by particle alignment. Ceramics International. https://doi.org/10.1016/j.ceramint.2016.01.103
    19. Korattanawittaya, S., Petcharoen, K., Sangwan, W., Tangboriboon, N., Wattanakul, K., & Sirivat, A. (2017). Durable compliant electrode based on graphene and natural rubber. Polymer Engineering and Science. https://doi.org/10.1002/pen.24392
    20. Kultzow, R., & Mainguy, B. (2001). Low dielectric constant and low shrinkage epoxy system for power electronics applications. Proceedings of the Electrical/Electronics Insulation Conference. https://doi.org/10.1109/EEIC.2001.965629
    21. Lewis, J. S., Barani, Z., Magana, A. S., Kargar, F., & Balandin, A. A. (2019). Thermal and electrical conductivity control in hybrid composites with graphene and boron nitride fillers. Materials Research Express. https://doi.org/10.1088/2053-1591/ab2215
    22. Li, Y., Zhang, H., Porwal, H., Huang, Z., Bilotti, E., & Peijs, T. (2017). Mechanical, electrical and thermal properties of in-situ exfoliated graphene/epoxy nanocomposites. Composites Part A: Applied Science and Manufacturing. https://doi.org/10.1016/j.compositesa.2017.01.007
    23. Lindley, D. V. (1980). Approximate Bayesian methods. Trabajos de Estadistica Y de Investigacion Operativa, 31(1), 223–245. https://doi.org/10.1007/BF02888353
    24. Luo, S., Shen, Y., Yu, S., Wan, Y., Liao, W. H., Sun, R., & Wong, C. P. (2017). Construction of a 3D-BaTiO3 network leading to significantly enhanced dielectric permittivity and energy storage density of polymer composites. Energy and Environmental Science. https://doi.org/10.1039/c6ee03190k
    25. Marra, F., D’Aloia, A. G., Tamburrano, A., Ochando, I. M., De Bellis, G., Ellis, G., & Sarto, M. S. (2016). Electromagnetic and dynamic mechanical properties of epoxy and vinylester-based composites filled with graphene nanoplatelets. Polymers. https://doi.org/10.3390/polym8080272
    26. Marsden, A. J., Papageorgiou, D. G., Vallés, C., Liscio, A., Palermo, V., Bissett, M. A., Young, R. J., & Kinloch, I. A. (2018). Electrical percolation in graphene-polymer composites. In 2D Materials. https://doi.org/10.1088/2053-1583/aac055
    27. Mather, P. T., Luo, X., & Rousseau, I. A. (2009). Shape memory polymer research. In Annual Review of Materials Research. https://doi.org/10.1146/annurev-matsci-082908-145419
    28. McGrail, B. T., Sehirlioglu, A., & Pentzer, E. (2015). Polymer composites for thermoelectric applications. Angewandte Chemie - International Edition. https://doi.org/10.1002/anie.201408431
    29. Mekala, R., & Badi, N. (2013). Modeling and Simulation of High Permittivity Core-shell Ferroelectric Polymers for Energy Storage Solutions. COMSOL Conference.
    30. Ming, P., Zhang, Y., Bao, J., Liu, G., Li, Z., Jiang, L., & Cheng, Q. (2015). Bioinspired highly electrically conductive graphene-epoxy layered composites. RSC Advances. https://doi.org/10.1039/c5ra00233h
    31. Oladele, I. O., Omotosho, T. F., & Adediran, A. A. (2020). Polymer-Based Composites: An Indispensable Material for Present and Future Applications. International Journal of Polymer Science, 2020, 1–12. https://doi.org/10.1155/2020/8834518
    32. Pant, H. C., Patra, M. K., Verma, A., Vadera, S. R., & Kumar, N. (2006). Study of the dielectric properties of barium titanate-polymer composites. Acta Materialia. https://doi.org/10.1016/j.actamat.2006.02.031
    33. Pathak, A. K., Borah, M., Gupta, A., Yokozeki, T., & Dhakate, S. R. (2016). Improved mechanical properties of carbon fiber/graphene oxide-epoxy hybrid composites. Composites Science and Technology. https://doi.org/10.1016/j.compscitech.2016.09.007
    34. Phan, T. T. M., Chu, N. C., Luu, V. B., Nguyen Xuan, H., Martin, I., & Carriere, P. (2016). The role of epoxy matrix occlusions within BaTiO3 nanoparticles on the dielectric properties of functionalized BaTiO3/epoxy nanocomposites. Composites Part A: Applied Science and Manufacturing. https://doi.org/10.1016/j.compositesa.2016.08.018
    35. Phan, T. T. M., Chu, N. C., Luu, V. B., Nguyen Xuan, H., Pham, D. T., Martin, I., & Carrière, P. (2016). Enhancement of polarization property of silane-modified BaTiO3 nanoparticles and its effect in increasing dielectric property of epoxy/BaTiO3 nanocomposites. Journal of Science: Advanced Materials and Devices. https://doi.org/10.1016/j.jsamd.2016.04.005
    36. Popielarz, R., & Chiang, C. K. (2007). Polymer composites with the dielectric constant comparable to that of barium titanate ceramics. Materials Science and Engineering B: Solid-State Materials for Advanced Technology. https://doi.org/10.1016/j.mseb.2007.01.035
    37. R. Byron Bird Warren E. Stewart Edwin N. Lightfoo, Bird, R. B., Stewart, W. E., & Lightfoot, E. N. (2006). Transport Phenomena, Revised 2nd Edition. John Wiley & Sons, Inc.
    38. Rosner, G. L. (2020). Bayesian Methods in Regulatory Science. Statistics in Biopharmaceutical Research, 12(2), 130–136. https://doi.org/10.1080/19466315.2019.1668843
    39. Schumacher, J., Fideu, P., Ziegmann, G., & Herrmann, A. (2009). A Consistent Environment for the Numerical Prediction of the Properties of Composite Materials. COMSOL Conference.
    40. Shahil, K. M. F., & Balandin, A. A. (2012a). Graphene-multilayer graphene nanocomposites as highly efficient thermal interface materials. Nano Letters. https://doi.org/10.1021/nl203906r
    41. Shahil, K. M. F., & Balandin, A. A. (2012b). Thermal properties of graphene and multilayer graphene: Applications in thermal interface materials. Solid State Communications. https://doi.org/10.1016/j.ssc.2012.04.034
    42. Tang, G., Jiang, Z. G., Li, X., Zhang, H. Bin, Hong, S., & Yu, Z. Z. (2014). Electrically conductive rubbery epoxy/diamine-functionalized graphene nanocomposites with improved mechanical properties. Composites Part B: Engineering. https://doi.org/10.1016/j.compositesb.2014.08.013
    43. Tomer, V., Polizos, G., Manias, E., & Randall, C. A. (2010). Epoxy-based nanocomposites for electrical energy storage. I: Effects of montmorillonite and barium titanate nanofillers. Journal of Applied Physics. https://doi.org/10.1063/1.3487275
    44. van de Schoot, R., Kaplan, D., Denissen, J., Asendorpf, J. B., Neyer, F. J., & van Aken, M. A. G. (2014). A Gentle Introduction to Bayesian Analysis: Applications to Developmental Research. Child Development, 85(3), 842–860. https://doi.org/10.1111/cdev.12169
    45. Wang, Z., Nelson, J. K., Koratkar, N., Schadler, L. S., Hillborg, H., & Zhao, S. (2011). Dielectric properties of electrospun barium titanate fibers/graphene/ silicone rubber composites. Annual Report - Conference on Electrical Insulation and Dielectric Phenomena, CEIDP. https://doi.org/10.1109/CEIDP.2011.6232738
    46. Wang, Zepu, Nelson, J. K., Miao, J., Linhardt, R. J., Schadler, L. S., Hillborg, H., & Zhao, S. (2012). Effect of high aspect ratio filler on dielectric properties of polymer composites: A study on barium titanate fibers and graphene platelets. IEEE Transactions on Dielectrics and Electrical Insulation. https://doi.org/10.1109/TDEI.2012.6215100
    47. Yousefi, N., Sun, X., Lin, X., Shen, X., Jia, J., Zhang, B., Tang, B., Chan, M., & Kim, J. K. (2014). Highly aligned graphene/polymer nanocomposites with excellent dielectric properties for high-performance electromagnetic interference shielding. Advanced Materials, 26(31), 5480–5487. https://doi.org/10.1002/adma.201305293
    48. Zandiatashbar, A., Lee, G. H., An, S. J., Lee, S., Mathew, N., Terrones, M., Hayashi, T., Picu, C. R., Hone, J., & Koratkar, N. (2014). Effect of defects on the intrinsic strength and stiffness of graphene. Nature Communications. https://doi.org/10.1038/ncomms4186
    49. Zhang, C., Chi, Q., Dong, J., Cui, Y., Wang, X., Liu, L., & Lei, Q. (2016). Enhanced dielectric properties of poly(vinylidene fluoride) composites filled with nano iron oxide-deposited barium titanate hybrid particles. Scientific Reports. https://doi.org/10.1038/srep33508
    50. Zhao, S., Chang, H., Chen, S., Cui, J., & Yan, Y. (2016). High-performance and multifunctional epoxy composites filled with epoxide-functionalized graphene. European Polymer Journal. https://doi.org/10.1016/j.eurpolymj.2016.09.036

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    Computational prediction of electrical and thermal properties of graphene and BaTiO3 reinforced epoxy nanocomposites. (2021). Biomaterials and Polymers Horizon, 1(1), 1-14. https://doi.org/10.37819/bph.001.01.0132
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    Computational prediction of electrical and thermal properties of graphene and BaTiO3 reinforced epoxy nanocomposites. (2021). Biomaterials and Polymers Horizon, 1(1), 1-14. https://doi.org/10.37819/bph.001.01.0132

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    Raghvendra Kumar Mishra
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    Saurav Goel
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